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(13) The complexity of the electronic structure of the naked U 2 was already pointed out in 1990, (1,14) but it was not until 2005 when Gagliardi and Roos predicted using CASPT2 calculations that U 2 is a stable molecule in the gas phase with a dissociation energy of about 30 kcal (11) Mass spectrometric evidence has been reported on the formation of Th 2 and U 2 in gas phase (12) as well as the isolation and characterization of uranium hydride molecules. Since the initial studies, it became clear that the propensity to form U-ligand bonds was greater than that for forming U–U bonds. (8−10) Nevertheless, much less experimental information is available about the formation of diactinides. (4) Huge advances have been made in the chemistry of the f-elements over the last decades, (5,6) including the synthesis of complexes containing actinide–ligand multiple bonds, (7) or uranyl peroxide capsules with high oxidation states. (1−3) In nature, uranium is generally found as an oxide, showing several oxidation states. Understanding how atoms stay together to form stable structures is at the core of chemistry. In general, metal ions within fullerenes should be regarded as templates in cage formation, not as statistically confined units that have little chance of being observed. Although 5f–5f interactions are responsible for the covalent interactions at distances close to 2.5 Å, overlap between 7s6d orbitals is still detected above 4 Å. Smaller cages like C 60 exhibit the two interactions, and a strong triple U–U bond with an effective bond order higher than 2 is observed. The formation of U–U bonds competes with U–cage interactions that tend to separate the U ions, hindering the observation of short U–U distances in the crystalline structures of diuranium endofullerenes as in U 80. DFT, CASPT2 calculations, and MD simulations for several fullerenes of different sizes and symmetries showed that thanks to the formation of strong U(5f 3)-U(5f 3) triple bonds, two U 3+ ions can be incarcerated inside the fullerene. To evaluate the feasibility of covalent U–U bonds, which are neglected in classical actinide chemistry, we have first investigated the formation of smaller diuranium EMFs by laser ablation using mass spectrometric detection of dimetallic U 2n species with 2 n ≥ 50. Previous characterizations of diactinide endohedral metallofullerenes (EMFs) Th 80 and U 80 have shown that although the two Th 3+ ions form a strong covalent bond within the carbon cage, the interaction between the U 3+ ions is weaker and described as an “unwilling” bond.
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As Drupal 7 teetered towards end-of-life and with Drupal 8/9 stepping into the limelight, it was natural to assume active development (read community support) in the Drupal 7 space would slow way, way down. Or more specifically it’s Drupal 7 and PHP 7.x EOL, both of which were threatening the continued success of the platforms. But there is a problem: SOLO and SSF were built on Drupal 7. The user base for the platforms is steadily growing, and the future of the software looks bright. The unrealized ambitions for the software (the product backlog) is a manicured and prioritized list of features with realistic aspirations toward some future sprint. They are living products that continue to release new features on a regular schedule, and still very much embody the product owner’s realized ambitions for the software. The platforms utilize more than fifty contributed modules and more than thirty custom modules built-to-order for extremely specific stakeholder needs. SOLO and SSF are the result of more than sixty coding sprints and an equal number of structured planning and feedback cycles. The platforms serve nearly a dozen distinct audiences, generate longform PDFs from fielded and WYSIWYG content, serve up large datasets as dynamically generated Zip and CSV downloads, integrate with a variety of APIs, and deliver dozens of automated notifications that nudge application review processes along their various workflows. The two websites facilitate the assessment of thousands of applicants each year for research, education, and funding opportunities that require diverse stakeholders to participate in multi-step evaluation processes.Īten Design Group and Stanford’s Research Information Technology & Innovation team (RITI) have been actively expanding the two sites and introducing new suites of features for more than five years. They are now application workflow management platforms that organize and streamline a wide variety of communication, collaboration, and evaluation processes. SOLO and SSF became complex and feature rich. The platforms gained traction, picked up users, and grew. Stanford Seed Funding (SSF) and Stanford On and Off-Campus Learning Opportunities (SOLO) began in 2015 as an ambitious idea, an excited team, and a lean proof of concept built on Drupal 7. Importantly, it is dramatically more cost effective than the alternatives. Why is that? The short answer is that Backdrop CMS is an upgrade-in-place for Drupal 7 that resolves end-of-life (EOL) concerns and facilitates further feature development. I’ll save you some skimming: Upgrading from Drupal 7 to Backdrop CMS is a good fit if you’re happy with your existing platform. Webmasters, marketing and communications teams, and product owners everywhere are asking the same question: What’s next for my Drupal 7 platform?īackdrop CMS is just one of a variety of upgrade paths for your Drupal 7 website - but in special cases it’s the right one. Drupal 7 is wobbling towards end-of-life, with PHP 7.x close by its side. As a kid, it hit me like a ton of bricks and, when I found out that I was going to be a father, the very first thing I ever bought for my yet-to-be-born daughter was her very own copy of The Phantom Tollbooth. I’ve written about The Phantom Tollbooth at considerable length in the past ( here and here and here), largely because I think it’s one of the most profound books I’ve ever read. Rowling’s world…Īny fans of kidlit need to see this documentary…īack in October 2011, I contributed to a Kickstarter campaign by filmmaker Hannah Jayanti, who wanted to create an original documentary to celebrate the fiftieth anniversary of The Phantom Tollbooth, a children’s classic written by Norton Juster and illustrated by Jules Feiffer. Here are some pictures of our nerdy parents having DIY fun in J.K. It was a whole lot of fun and I’m proud of what we accomplished on a very small budget in a very small amount of time. (I was a masked Death Eater who jumped out from behind a curtain, yelled “Avada Kedavra!”, and pointed my wand at them – which was really an air-compressor hose that loudly sprayed a stream of air at them, making the kids scream and run out the exit.) They then moved onto Diagon Alley, getting harassed by goblins all the way, until they ended up in a graveyard where Voldemort and some masked Death Eaters were waiting for them. Next, they went through a pitch-black Forbidden Forest, where they got whomped by parents in Whomping Willow costumes and almost got eaten by a giant spiders. Instead, the students entered a hallway in Hogwarts (complete with floating candles and talking pictures) where Professor McGonagall warned them that Voldemort and the Death Eaters were on the rise. (The costume was tricky and we couldn’t figure out a good “Dementor Kiss” effect.) We’re dealing with it.) Originally, we hit onto the idea because we thought that it would be really creepy to have Dementors going after the kids, but, after a few weeks of planning, we didn’t end up having Dementors at all. It made the kidlit/ Potter-nerd in me completely geek out and it couldn’t have been more perfect because my daughter is currently reading Harry Potter and the Order of the Phoenix. This year – and I couldn’t have been happier about this – the theme was HAUNTED HOGWARTS. But WEEKS of planning happens before that short set-up time, particularly regarding the “theme” of the haunted house, which has to be both appropriate and interesting for elementary school kids. Actually, it’s called The Haunted Hallway because, basically, we have a few hours to transform two sections of school hallway into something that can creep out a K-6 audience. Two weeks ago, my daughter’s elementary school had their annual Fall Festival and I got talked into… I mean, I got the privilege of helping head up the haunted house. Phil McGraw, Suze Orman, Kelly Osbourne, Sarah Ferguson, Duchess of York… the list goes on and on. Not only does the book collect my heartfelt letter to my mom, but it also collects letters from celebrities like Melissa Rivers, Shania Twain, will.i.am, Christy Turlington, Kristin Chenoweth, Mariel Hemingway, Josh Groban, Monica Lewinsky, Dr. I am 100% biased when I say that it would make a great Mother’s Day gift, but I’m allowed, right? It’s my first legitimate book credit.Īnd, oh boy, the company I get to keep in this book is SURREAL. (She’s really pretty great.) Well, the book was just released and it’s now on sale. She has sacrificed a lot for my sister and I over the years and she loves and nurtures my daughter in the tradition of the best kind of grandparents, so I was very happy to be given such a unique opportunity to say “thanks” to her in such a public setting. (It was the continuation of a series started by Lisa Erspamer – the previous volumes were A Letter to My Cat and A Letter to My Dog.) I was asked to contribute to an anthology titled A Letter to My Mom, a book of letters written by celebrities and normal folk (like myself) in which we all take a moment to thank our moms for, well, being moms. My mom is getting a pretty cool Mother’s Day gift this year…Ī few months back, I got a very unusual invitation. Freytag’s Pyramidįreytag’s Pyramid is a visual representation of the basic elements of a good story arc. It is the hook that draws in the reader and allows them to follow along on the journey and see how the characters change and grow. The inciting incident is what gives a story its structure and purpose. Without this moment, a story would simply be a series of events with no clear purpose or direction. Regardless of its size, the inciting incident must be significant enough to change the course of the story. The inciting incident can be something small, like a character receiving a letter, or something big, like a natural disaster. Typically occurring early on in the story, this pivotal event thrusts the main character on their journey, and it sets the tone for the rest of the narrative. The inciting incident of a story is the catalyst that sets the story in motion. How Does the Inciting Incident of a Story Fit Into Overall Story Structure? Regardless of its source, the inciting incident creates tension and conflict, driving the story forward and keeping readers engaged. In others, it is an external force that throws the character’s life into chaos. In some cases, it is a direct result of the main character‘s choices or actions. Some would say that this is when the real story starts. It is often the catalyst for change, spurring the protagonist to action along a new path. The inciting incident occurs early on in the story, typically after the main character’s normal world is introduced, and its effects are felt throughout the entire plot. Without this key ingredient, the story would lack purpose and direction. In storytelling, the inciting incident is the event or circumstance that sets in motion the main conflict of the story. Let’s start with the inciting incident definition. What is the Inciting Incident in a Story? Summary: What is the Inciting Incident of a Story?.Common Questions About The Inciting Incident in a Story.Example 2: Harry Potter and The Sorcerer's Stone.What Are Good Examples of an Inciting Incident in A Story?.How Do I Write an Inciting Incident for a Subplot?.How do I Write The Inciting Incident in A Story?.Can I Skip an Inciting Incident in My Story?.What Happens After the Inciting Incident in a Story?.Why Is It Important to Have an Inciting Incident in a Story?.How Does the Inciting Incident of a Story Fit Into Overall Story Structure?.What is the Inciting Incident in a Story?. As Gattis allowed himself to open up, Poggi saw that it created an even more interesting dynamic.īTW, in the comments, Feldman says that Fox covering Michigan four weeks in a row "DEFINITELY helped find this story and develop a better feel for what it was. The first-time offensive coordinator acknowledged that he sometimes felt like he didn’t have the group’s support or confidence, which had made things difficult. I see a coach that is answering questions in a non-confident way because he doesn’t know if the question is a ‘gotcha’ question or an ‘I’m-on-the-team’ question. Poggi has helped Michigan get out to a 10-0 start and the No. He helped lead the team to a 2021 Big Ten championship and the College Football Playoffs. I see a coach that is looking over his shoulder. Poggi was critical in turning the Wolverines program around. “Jim’s hired him to be the coordinator, and because of that he’s got to have confidence, and right now I see a coach that doesn’t have confidence. An investment manager, Poggi coached for over twenty years at the Gilman School (19962015) and Saint Frances Academy (20172020) in Baltimore, and also several years as an off-field analyst for the Michigan Wolverines under head coach Jim Harbaugh. He’s been hired as a coordinator whether anybody in this room likes it, or doesn’t like it. And we want to get to the college football playoff. We want to win the AAC and we want to win it repeatedly. Poggi on his goal as a program: Our goal is very simple. Biff Poggi didn’t agree to terms with the Charlotte 49ers to leave the Michigan Wolverines program to mess around. And we’re gonna fail as an organization because of this,” Poggi said. Coach Poggi clearly defined his expectations for the program. They wanted more of what Harbaugh had done in his Stanford days - quarterback under center, using a fullback, things they knew the head coach liked. Annual tuition at the school, which reported an enrollment of 161 at the start of the 2018. He is running a hedge fund and real estate private investment fund for the firm. The 49ers introduced Francis 'Biff' Poggi as the third head coach in program history on Monday. “There’s support here, but it’s divided between Josh and what he wants to do, and some other legacy ideas.” To Poggi, Gattis knew the system that he’d learned under Joe Moorhead well, but several other assistants weren’t on board. According to the Archdiocese of Baltimore, Poggi funded scholarships for more than 40 players last year. Biff Poggi is still coaching football and growing boys into men at St. It suggests that Comrade Gattis did help to modernize the Harbaugh offense, and that after Gattis left, the Hegelian dialectic between manball and modern concepts was preserved. Whether the action is in contract, tort, (including negligence) or other tortious action. The Only Mortgage Calculator Youll Ever Need. 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Restrictions may apply, contact GR Affinity for current rates and more information.Īll information provided in this publication is for informational and educational purposes only, and in no way is any of theĬontent contained herein to be construed as financial, investment or legal advice or instruction. Receipt of application does not represent an approvalįor financing or interest rate guarantee. Not all applicants will be approved for financing. Applicant subject to creditĪnd underwriting approval. Mortgage insurance is only available when the purchase price is below 1,000,000. Specific to the circumstances of any individual and should not be relied upon in that regard. Before you apply, get an idea of how much you could afford for purchase or save with a. Sample rate provided for illustration purposes only and is not intended to provide mortgage or other financial advice Use our mortgage calculator to estimate your mortgage payments. 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